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Protein and Peptide Letters, Vol. 8, No. 6, 2001

 

Contents

 

Regular Papers

In vitro Degradation of b-Amyloid[25-35] Peptide Pp.423-428

Krisztina Jost, József Varga, Botond Penke and Márta Zarándi

[Abstract]

 

An Efficient, Flexible-Model Program for the Analysis of Differential Scanning Calorimetry Protein Denaturation Data Pp.429-436

Sasha B. Grek, John K. Davis and Michael Blaber

[Abstract]

 

Modeling the Hierarchical Protein Folding Using Clustering Monte-Carlo Algorithm Pp.437-442

Semen O. Yesylevskyy and Alexander P. Demchenko

[Abstract]

 

Synthesis and Characterization of New Temporin A Analogs and A Hybrid Peptide Pp.443-450

David Wade, Tomas Bergman, Jerzy Silberring and Hilkka Lankinen

[Abstract]

 

Interaction of An Amphipathic Peptide Corresponding to Residues 417-434 of Escherichia coli Haemolysin with Phospholipid Bilayers Pp.451-460

Georgina Verza, Félix M. Gońi and Laura S. Bakás

[Abstract]

 

Syntheses of Neurotensin (NT) Analogues and Their Comparative Anorectic Effect on Food Intake in Rats Pp.461-468

T. Abiko and Y. Takamura

[Abstract]

 

CDNA Cloning and Expression of Acutin II, A Native Mutant of Thrombin-Like Enzyme from Agkistrodon acutus Pp.469-475

Hua Pan, Jiewu Liu, Xiaoyan Du, Yuancong Zhou and Xiangfu Wu

[Abstract]

 

Renal Effects of the Lectin from Canavalia brasiliensis Seeds Pp.477-484

Edson H. Teixeira, Alexandre Havt, Paulo S.F. Barbosa,  Dalgimar B. Meneses, Manassés C. Fonteles, Helena S.A. Monteiro, Alexandre H. Sampaio and Benildo S. Cavada

[Abstract]

 

Serine Protease Inhibitors from Amazon Leguminosae Seeds: Purification and Preliminary Characterization of Two Chymotrypsin Inhibitors from Inga umbratica Pp.485-493

Calderon, L.A., Teles, R.C.L., Leite, J.R.S.A., Bloch, C. Jr., Astolfi-Filho, S. and Freitas, S.M.

[Abstract]

 

Crystallization Reports                                                                                                                 

Crystallization and Preliminary X-Ray Studies of A Thermostable DNA Photolyase from Thermus thermophilus HB8 Pp.495-498

Hirofumi Komori, Hiroshi Tsujiuchi, Ryoji Masui, Seiki Kuramitsu, Shigeyuki Yokoyama, Takehiko Shibata, Yorinao Inoue and Kunio Miki

[Abstract]

 

Preliminary X-Ray Crystallographic Studies of the Mycobacterium tuberculosis HSP16.3 Molecular Chaperone Pp.499-502

Chen Y., An J., Ding Y. Dai H., Mao Q., Feng L., Liu B., Chang Y., Chen F., He H., Tang H., Chang Z. and Rao Z.

[Abstract]

 

Crystallization and Preliminary X-Ray Crystallographic Studies of Staphylokinase Variant S41G Pp.503-507

Chen Y., An J., Song G., Feng L., Ding Y., Chang Y., Chen F., Liu B., He H., Tang H., Song H. and Rao Z.

[Abstract]

 

 

Abstracts

 

[Back to top] In vitro Degradation of b-Amyloid[25-35] Peptide 

Krisztina Jost, József Varga, Botond Penke and Márta Zarándi

 

Some amyloid-derived peptides show their toxic effects only after a long “aging” period performed several days at pH 7.4 and 37 °C for cluster formation. Our experiments show that long aging of b-amyloid[25-35] under physiological conditions results in peptide bond cleavage between Asn27 and Lys28. Relatively short incubation time (24 hours) and absence of Ca2+ ions prevent peptide cleavage and results in good aggregation of b-amyloids.

 

[Back to top] An Efficient, Flexible-Model Program for the Analysis of Differential Scanning Calorimetry Protein Denaturation Data  

Sasha B. Grek, John K. Davis and Michael Blaber

 

Although thermodynamic formalisms for protein denaturation have been established for some time, available software programs for deconvolution of DSC data exhibit various limitations. These include enforcing a constant DCp(T), linear heat capacity functions, and so on. We have developed a Windows™ based program that allows greater flexibility, speed and accuracy than previously available programs for the analysis of DSC data.  One novel feature of the program is the inclusion of, and ability to refine, a concentration-dependent term.

 

[Back to top] Modeling the Hierarchical Protein Folding Using Clustering Monte-Carlo Algorithm  

Semen O. Yesylevskyy and Alexander P. Demchenko

 

A new modification of Monte-Carlo algorithm was suggested for the simulation of hierarchical protein folding. When applied to 2D lattice model of 12-member peptide this method allows observing complex kinetic folding behavior with the formation of clustered intermediates.

           

[Back to top] Synthesis and Characterization of New Temporin A Analogs and A Hybrid Peptide 

David Wade, Tomas Bergman, Jerzy Silberring and Hilkka Lankinen

 

Temporin A is one of a group of 31 structurally similar antibiotic peptides isolated from the skins of anurans, 10 of which were isolated from the European red frog, Rana temporaria.  The synthesis and bacteriological study of temporin A and 8 analogs were reported previously, and this article describes the synthesis and analyses of 11 new temporin A analogs, and a cecropin A-temporin A hybrid peptide

 

[Back to top] Interaction of An Amphipathic Peptide Corresponding to Residues of Escherichia coli Haemolysin with Phospholipid Bilayers  

Georgina Verza, Félix M. Gońi and Laura S. Bakás

 

a-Haemolysin is an extracellular protein toxin (107KDa) produced by certain pathogenic strains of Escherichia coli. It can bind to lipid bilayers and produce membrane disruption in cell and model membranes. Protein secondary structure predictions suggest an amphipathic helix conformation for the membrane-interacting domain of HlyA, and no potential transmembrane segments. In this paper, we investigated the lipid associating properties of the chemically synthesized peptide H9 (MFEHVASKMADVIAEWEK) corresponding to residues 417-434 of HlyA. Changes in the intrinsic fluorescence and fluorescence anisotropy of the single Trp residue after the addition of DMPC-LUV reveal that the peptide-membrane interaction is optimum at or above the gel-liquid crystalline transition temperature of the lipid. Moreover, the peptide induces vesicle aggregation, as detected through changes in light scattering by the vesicle suspension. However, under comparable conditions, H9 has no hemolytic activity against sheep erythrocytes, nor does it induce leakage of vesicular aqueous contents. These data suggest that HlyA binds the membrane surface through amphipathic helices, though  cooperativity among neighbouring helices is probably necessary to explain the lytic effect of the toxin.

 

[Back to top] Syntheses of Neurotensin (NT) Analogues and Their Comparative Anorectic Effect on Food Intake in Rats

T. Abiko and Y. Takamura

 

Five analogues of neurotensin (NT: Pyr-Leu-Tyr-Glu-Asn-Lys-Pro-Arg-Arg-Pro-Tyr-Ile-Leu) were prepared by the solid-phase method and their comparative anorectic effects on food intake in rats were examined. Among them, [Phe(NO2)3,11]-NT and [Phe(4F)3,11]-NT showed stronger anorectic activity than that of the parent peptide but [Tyr(Me)3,11]-NT was less active than the parent peptide. On the contrary, the other two analogues, [Sar7,10]-NT and [βAla7,10]-NT had no anorectic activity.

 

[Back to top] CDNA Cloning and Expression of Acutin II, A Native Mutant of Thrombin-Like Enzyme from Agkistrodon acutus  

Hua Pan, Jiewu Liu, Xiaoyan Du, Yuancong Zhou and Xiangfu Wu

 

One cDNA of a thrombin-like enzyme named acutinII was amplified by RT-PCR from the venom gland of the Agkistrodon acutus snake. AcutinII shows high similarity to acutin, the other thrombin-like enzyme from Agkistrodon acutus snake in nucleotide and amino acid sequences except it is shorter by 16 amino acid at the C-terminus. The catalytic residues and disulfide bridges of acutinII were deduced. AcutinII was expressed in E. coli .The expressed protein was detected by western blotting and the yield was up to 32% of the total proteins.

 

[Back to top] Renal Effects of the Lectin from Canavalia brasiliensis Seeds 

Edson H. Teixeira, Alexandre Havt, Paulo S.F. Barbosa,  Dalgimar B. Meneses, Manassés C. Fonteles, Helena S.A. Monteiro, Alexandre H. Sampaio and Benildo S. Cavada

 

The lectin from the seeds of Canavalia brasiliensis (Con Br) was tested for its renal effects using the isolated perfusion rat kidney method. Three different doses were examined (3, 10 and 30 mg/ml), which were compared with a control group. The control group was perfused with only Krebs-Henseleit solution containing 6% BSA. Con Br caused diuresis and natriuresis, with a mild alteration on the perfusion pressure. Probably the lectin is inhibiting the Na+/K+/2Cl- transporter present in the thick ascending limb of the Henle´s loop.

 

[Back to top] Serine Protease Inhibitors from Amazon Leguminosae Seeds: Purification and Preliminary Characterization of Two Chymotrypsin Inhibitors from Inga umbratica  

Calderon, L.A., Teles, R.C.L., Leite, J.R.S.A., Bloch, C. Jr.,  Astolfi-Filho, S. and Freitas, S.M.

 

Nine species of Leguminosae seeds from Amazon forest have been screened for trypsin and chymotrypsin inhibitory activity.  The species involved were Cassia basselari, Cassia grandis, Cassia occidentalis, Dialium guianense, Inga fagifolia, Inga rubiginosa, Inga umbratica, Inga velutina and Mimosa guillandinae. Extracts from all the species, except I. umbratica, contained significant activity against trypsin, chymotrypsin and blood human clotting factors Xa. Two new chymotrypsin inhibitors (IuCI-1 and IuCI-2) have been purified to homogeneity from I. umbratica with molecular masses of 20,088.6 and 20,271.2, respectively.

 

[Back to top] Crystallization and Preliminary X-Ray Studies of A Thermostable DNA Photolyase from Thermus thermophilus HB8  

Hirofumi Komori, Hiroshi Tsujiuchi, Ryoji Masui, Seiki Kuramitsu, Shigeyuki Yokoyama, Takehiko Shibata, Yorinao Inoue and Kunio Miki

 

A thermostable DNA photolyase from an extremely thermophilic bacterium, Thermus thermophilus HB8 has been crystallized by the hanging drop vapor diffusion method using NH4H2PO4 as a precipitant.   The hexagonal crystals were grown to a size of 0.4 mm in length.  X-ray diffraction experiments show the crystals to belong to the hexagonal space group P6522 or P6122 with the unit cell dimensions of a=b=113.6 Ĺ, c=142.0 Ĺ.   They diffract X-rays to 2.4 Ĺ resolution with synchrotron radiation.

 

[Back to top] Preliminary X-Ray Crystallographic Studies of the Mycobacterium tuberculosis HSP16.3 Molecular Chaperone 

Chen Y., An J., Ding Y. Dai H., Mao Q., Feng L., Liu B., Chang Y., Chen F., He H., Tang H., Chang Z. and Rao Z.

 

Mycobacterium Tuberculosis HSP16.3 is a major antigen maximally expressed during the stationary phase. Previous studies showed that HSP16.3 can function as a molecular chaperone in vitro. Here, crystallization trails of HSP 16.3 were reported. A kind of crystal can be diffracted to 2.8 Ĺ resolution at the "Photon Factory", a synchrotron light source in Japan. The crystal displayed the space group R3 with unit cell parameters a=b=110 Ĺ , c=152 Ĺ and γ=120˚. Assuming the presence of 9 HSP16.3 molecules in an asymmetric unit, it gives a Vm= 0.73 Ĺ 3/Da. and solvent content of 35% by volume.

 

[Back to top] Crystallization and Preliminary X-Ray Crystallographic Studies of Staphylokinase Variant S41G 

Chen Y., An J., Song G., Feng L., Ding Y., Chang Y., Chen F., Liu B., He H.,  Tang H., Song H. and Rao Z.

 

Staphylokinse (Sak) is a plasminogen activator for the treatment of patients with thrombolitic disorders. However, the highly purified Sak can form dimer in solution, which is believed to be the cause for the increased antigenicity. Here we report a new crystal form with two molecules in an asymmetric unit, suggesting there maybe a dimer packing in crystal. The crystal belongs to the orthorhombic space group P212121 and the unit cell dimensions are a=43.9, b=59.3, c=102.4 Ĺ, a=b=g=90ş. The diffraction data was 99.7% complete to 2.3 Ĺ with an Rmerge of 5.5%.